Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents.
نویسندگان
چکیده
Diastereoselective anti-aminooxygenation and anti-diamination of alkenes with amidines were enabled by hypervalent iodine(III) reagents such as PhI(OCOR)2 and PhI(NMs2)2, respectively. The present transformation offers diastereochemically pure dihydroimidazoles divergently from E- and Z-alkenes.
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ورودعنوان ژورنال:
- Organic letters
دوره 16 23 شماره
صفحات -
تاریخ انتشار 2014